A streamlined approach to particle ALD coating of spherical beads

TL;DR

This paper presents a simple, fast, and scalable static ALD process for uniformly coating spherical nanoparticles with materials like silica and titania, suitable for researchers new to particle ALD.

Contribution

It introduces a streamlined static ALD coating method that reduces complexity and time, enabling uniform nanoparticle coatings in 8-10 hours without advanced fluidized bed techniques.

Findings

Achieved uniform ALD coating on silica and titania nanoparticles.

Demonstrated process scalability to tens of milligrams or grams.

Tunable nanoparticle size and refractive index.

Abstract

Conformal Atomic Layer Deposition (ALD) of nanoparticles is an now an established nanofabrication concept employed by many researchers for applications such as creating diffusion barriers, tuning catalysis, or masking a toxic particle core with a biocompatible shell. To conformally coat many grams of nanoparticles with ALD, long precursor soaking steps, fluidized beds, vibrating stages, or rotary feedthroughs are typically needed. While these impressive advancements in ALD techniques dominate literature searches of particle ALD coating, such methods may lead to a more time-intensive or cost-prohibitive process than what is required by many typical academic researchers. Thus we have performed this study to explore the limits of static planar ALD particle coating, the simplest method to coat nanoparticles with an ALD film. Using an Arradiance GEMStar6 ALD system, we have explored a fast and simple static ALD particle coating process. Our protocol produces relatively small, but still academically useful, quantities of uniformally ALD-coated nanospheres. This process can be scaled up to nanoparticle samples in the tens of milligram to gram range. We have demonstrated that we can achieve silica or titania spherical particle synthesis, and then uniform ALD coating on the nanoparticles, all within 8-10 hours. The diameter of the chemically synthesized silica and titania nanoparticles is tunable from 50 nm up to greater than a micron. The refractive index of the titania nanoparticles is tunable from approximately 1.7 to 2.7. This report will be most useful for researchers who are new to particle ALD, or who want to experiment with core particles conformally covered with ALD shells before moving to a more complicated, higher throughput ALD method. We provide details for particle synthesis, storage, and ALD coating along with a comparison to more conventional approaches.