Colossal enhancement of electrical conductivity in Y2Ir2O7 nanoparticles

TL;DR

This study demonstrates that reducing particle size in Y2Ir2O7 enhances electrical conductivity and ferromagnetism, attributed to increased Iridium pentavalent states and altered spin interactions.

Contribution

It introduces a new chemical synthesis method for Y2Ir2O7 nanoparticles and links particle size reduction to significant property enhancements.

Findings

Nanocrystalline Y2Ir2O7 shows orders of magnitude higher electrical conductivity.

Enhanced ferromagnetism observed in nanocrystalline samples.

Increase in Iridium pentavalent states correlates with property changes.

Abstract

We present a comparative study of the magnetic and electrical properties of polycrystalline and nanocrystalline Y2Ir2O7, the latter prepared using a new chemical route. We find that reduction in particle size leads to enhanced ferromagnetism and orders of magnitude enhancement of electrical conductivity in the nanocrystalline sample. Based on x ray photoelectron spectroscopy and x ray absorption near edge structure spectroscopy results, the phenomenon is attributed to the increased fraction of pentavalent oxidation state of Iridium and the resulting increase in double exchange interaction along with the weakening of spin orbit coupling strength in the nanocrystalline sample compared to the bulk.