Experiments on thermoelectric properties of quantum dots

TL;DR

This paper reviews experimental studies on the thermoelectric properties of quantum dots, highlighting measurement techniques, theoretical comparisons, nonlinear effects, and future research directions in nanoscale thermoelectric phenomena.

Contribution

It provides a comprehensive overview of experimental methods and theoretical insights into the thermoelectric behavior of quantum dots, emphasizing recent nonlinear effects and open questions.

Findings

Thermoelectric response oscillates with gate potential.

Landauer calculations often better match experiments than single-electron models.

Nonlinear thermoelectric effects are increasingly studied.

Abstract

Quantum dots (QDs) are good model systems for fundamental studies of mesoscopic transport phenomena using thermoelectric effects because of their small size, electrostatically tunable properties and thermoelectric response characteristics that are very sensitive to small thermal biases. Here we provide a review of experimental studies on thermoelectric properties of single QDs realized in two-dimensional electron gases, single-walled carbon nanotubes and semiconductor nanowires. A key requirement for such experiments is methods for nanoscale thermal biasing. We briefly review the main techniques used in the field, namely, heating of the QD contacts, side heating and top heating, and touch upon their relative advantages. The thermoelectric response of a QD as a function of gate potential has a characteristic oscillatory behavior with the same period as is observed for conductance peaks. Much of the existing literature focuses on the agreement between experiments and theory, particularly for amplitude and line-shape of the thermovoltage $V_{th}$. A general observation is that the widely used single-electron tunneling approximation for QDs has limited success in reproducing measured $V_{th}$. Landauer-type calculations are often found to describe measurement results better despite the large electron-electron interactions in QDs. More recently, nonlinear thermoelectric effects have moved into the focus of attention and we offer a brief overview of experiments done so far. We conclude by discussing open questions and avenues for future work, including the role of asymmetries in tunnel- and capacitive couplings in thermoelectric behavior of QDs.