Nanosize effect: Enhanced compensation temperature and existence of magneto-dielectric coupling in SmFeO3

TL;DR

This study investigates nanoscale SmFeO3 particles, revealing size-dependent magnetic and dielectric properties, including enhanced compensation temperature and magneto-dielectric coupling, not seen in larger particles or bulk forms.

Contribution

It reports novel size-dependent magnetic and dielectric phenomena in SmFeO3 nanoparticles, including a six-fold increase in compensation temperature and coupled antiferromagnetic-ferroelectric transition.

Findings

Six-fold enhancement of compensation temperature in 55 nm particles

Unusual susceptibility rise between 550-630 K due to spin pinning

Coupled antiferromagnetic-ferroelectric transition observed in dielectric constant

Abstract

In transition metal oxides, quantum confinement arising from a large surface to volume ratio often gives rise to novel physico-chemical properties at nanoscale. Their size dependent properties have potential applications in diverse areas, including therapeutics, imaging, electronic devices, communication systems, sensors, and catalysis. We have analyzed structural, magnetic, dielectric, and thermal properties of weakly ferromagnetic SmFeO3 nanoparticles of sizes about 55 nm and 500 nm. The nano-size particles exhibit several distinct features that are neither observed in their larger-size variants nor reported previously for the single crystals. In particular, for the 55 nm particle, we observe six-fold enhancement of compensation temperature, an unusual rise in susceptibility in the temperature range 550 to 630 K due to spin pinning, and coupled antiferromagnetic-ferroelectric transition, directly observed in the dielectric constant.