A possible new family of unconventional high temperature superconductors

TL;DR

This paper proposes a new family of layered Co/Ni-based materials with specific electronic structures that could host unconventional high-temperature superconductivity, potentially surpassing existing high-Tc materials.

Contribution

It introduces a novel class of materials with specific lattice and electronic properties that may realize high-Tc superconductivity, unifying features of cuprates and iron-based superconductors.

Findings

Materials meet criteria for unconventional high-Tc superconductivity.

Predicted d-wave pairing symmetry with potentially higher T$_c$.

Provides a new platform for studying strongly correlated electrons.

Abstract

We suggest a new family of Co/Ni-based materials that may host unconventional high temperature superconductivity (high-T$_c$). These materials carry layered square lattices with each layer being formed by vertex-shared transition metal tetrahedra cation-anion complexes. The electronic physics in these materials is determined by the two dimensional layer and is fully attributed to the three near degenerated $t_{2g}$ d-orbitals close to a $d^7$ filling configuration in the d-shell of Co/Ni atoms . The electronic structure meets the necessary criteria for unconventional high T$_c$ materials proposed recently by us to unify the two known high-T$_c$ families, cuprates and iron-based superconductors. We predict that they host superconducting states with a d-wave pairing symmetry with T$_c$ potentially higher than those of iron-based superconductors. These materials, if realized, can be a fertile new ground to study strongly correlated electronic physics and provide decisive evidence for superconducting pairing mechanism.