Characterising molecules for fundamental physics: an accurate spectroscopic model of methyltrioxorhenium derived from new infrared and millimetre-wave measurements

TL;DR

This study provides a highly precise spectroscopic characterization of methyltrioxorhenium, improving understanding of its rotational and rovibrational structure, which is crucial for fundamental physics experiments like parity violation measurements.

Contribution

The paper presents new high-resolution infrared and millimetre-wave spectroscopic data and refined molecular parameters for methyltrioxorhenium, including isotopologues, using advanced spectroscopic techniques.

Findings

Refined rotational and hyperfine parameters up to J=43 and K=41.

Accurate rovibrational data across 6-300 K temperatures.

Determined hyperfine structure constants and centrifugal distortion parameters.

Abstract

Precise spectroscopic analysis of polyatomic molecules enables many striking advances in physical chemistry and fundamental physics. We use several new high-resolution spectroscopic devices to improve our understanding of the rotational and rovibrational structure of methyltrioxorhenium (MTO), the achiral parent of a family of large oxorhenium compounds that are ideal candidate species for a planned measurement of parity violation in chiral molecules. Using millimetre-wave and infrared spectroscopy in a pulsed supersonic jet, a cryogenic buffer gas cell, and room temperature absorption cells, we probe the ground state and the Re=O antisymmetric and symmetric stretching excited states of both CH3 187 ReO3 and CH3 185 ReO3 isotopologues in the gas phase with unprecedented precision. By extending the rotational spectra to the 150-300 GHz range, we characterize the ground state rotational and hyperfine structure up to J = 43 and K = 41, resulting in refinements to the rotational, quartic and hyperfine parameters, and the determination of sextic parameters and a centrifugal distortion correction to the quadrupolar hyperfine constant. We obtain rovibrational data for temperatures between 6 and 300 K in the 970-1015 cm-1 range, at resolutions down to 8 MHz and accuracies of 30 MHz. We use these data to determine more precise excited-state rotational, Coriolis and quartic parameters, as well as the ground-state centrifugal distortion parameter D K of the 187 Re isotopologue. We also account for hyperfine structure in the rovibrational transitions and hence determine the upper state rhenium atom quadrupole coupling constant eQq' .