Deformation of an Amorphous Polymer during the Fused-Filament-Fabrication Method for Additive Manufacturing

TL;DR

This paper models the deformation of amorphous polymer melts during fused filament fabrication, highlighting how flow-induced entanglement changes affect the polymer configuration in 3D printing.

Contribution

It introduces a modified Rolie-Poly model to simulate flow-induced entanglement changes during extrusion in FFF 3D printing.

Findings

Flow in corner geometry causes significant disentanglement.

Polymer configurations are highly affected by the extrusion process.

Model provides visualisation of complex polymer deformation.

Abstract

3D printing is rapidly becoming an effective means of prototyping and creating custom consumer goods. The most common method for printing a polymer melt is fused filament fabrication (FFF), and involves extrusion of a thermoplastic material through a heated nozzle; the material is then built up layer-by-layer to fabricate a three-dimensional object. Under typical printing conditions the melt experiences high strain rates within the FFF nozzle, which are able to significantly stretch and orient the polymer molecules. In this paper, we model the deformation of an amorphous polymer melt during the extrusion process, where the fluid must make a 90$^\text{o}$ turn. The melt is described by a modified version of the Rolie-Poly model, which allows for flow-induced changes in the entanglement density. The complex polymer configurations in the cross-section of a printed layer are quantified and visualised. The deposition process involving the corner flow geometry dominates the deformation and significantly disentangles the melt.