Pressure effects on the unconventional superconductivity of the noncentrosymmetric LaNiC2

TL;DR

This study combines ab initio calculations and Eliashberg theory to analyze pressure effects on LaNiC2's unconventional superconductivity, revealing pressure-dependent changes in electron-phonon coupling and suggesting a competing high-pressure phase.

Contribution

It provides a detailed first-principles analysis of LaNiC2's superconductivity under pressure, highlighting the role of Coulomb pseudopotential and electronic phase competition.

Findings

Superconducting parameters deviate from BCS predictions at zero pressure.

Electron-phonon coupling increases with pressure up to 15 GPa.

Disappearance of superconductivity at high pressure may be due to a new electronic phase.

Abstract

The unconventional superconductivity in the noncentrosymmetric LaNiC$_2$, and its evolution with pressure, is analyzed basing on the {\it ab initio} computations and the full Eliashberg formalism. First principles calculations of the electronic structure, phonons and the electron-phonon coupling are reported in the pressure range 0-15 GPa. The thermodynamic properties of the superconducting state were determined numerically solving the Eliashberg equations. We found that already at $p=0$ GPa, the superconducting parameters deviate from the BCS-type, and a large value of the Coulomb pseudopotential $\mu^{\star}=0.22$ is required to get the critical temperature $T_c = 2.8$~K consistent with experiment. If such $\mu^{\star}$ is used, the Eliashberg formalism reproduces also the experimentally observed values of the superconducting order parameter, the electronic specific heat jump at the critical temperature, and the change of the London penetration depth with temperature. This shows, that deviation of the above-mentioned parameters from the BCS predictions do not prejudge on the triplet or multiple gap nature of the superconductivity in this compound. Under the external pressure, calculations predict continuous increase of the electron-phonon coupling constant in the whole pressure range 0-15~GPa, consistent with the experimentally observed increase in $T_c$ for the pressure range 0-4~GPa, but inconsistent with the drop of $T_c$ above 4~GPa and the disappearance of the superconductivity above 7~GPa, reported experimentally. The disappearance of superconductivity may be accounted for by increasing the $\mu^{\star}$ to 0.36 at 7~GPa, which supports the hypothesis of the formation of a new high-pressure electronic phase, which competes with the superconductivity.