Colloidal Joints with Designed Motion Range and Tunable Joint Flexibility

TL;DR

This paper introduces a method to create colloidal joints with controllable motion range and flexibility using surface mobile DNA linkers, enabling programmable self-assembly for nanorobots and switchable materials.

Contribution

The authors develop a facile technique to produce anisotropic colloidal particles with tunable joint flexibility and motion range through DNA linker concentration and shape control.

Findings

DNA linker concentration tunes joint flexibility

Colloidal shape influences motion range due to curvature effects

Demonstrated creation of flexible colloidal molecules and polymers

Abstract

The miniaturization of machines towards the micron and nanoscales requires the development of joint-like elements that enable and constrain motion. We present a facile method to create colloidal joints, that is, anisotropic colloidal particles containing surface mobile DNA linkers that control the motion range of bonded particles. We demonstrate quantitatively that we can control the flexibility of these colloidal joints by tuning the DNA linker concentration in the bond area. We show that the colloidal shape controls the range of motion that these colloidal joints enable, due to the finite-sized patch of bonded linkers that cannot cross regions of high curvature. Finally we demonstrate the potential of the colloidal joints for programmable bottom-up self-assembly by creating flexible colloidal molecules and colloidal polymers. The reconfigurability and motion constraint offered by our colloidal joints make them promising building blocks for the development of switchable materials and nanorobots.