Enhancing Thermoelectric Performance Using Nonlinear Transport Effects

TL;DR

This paper investigates how nonlinear transport effects can significantly improve the efficiency and power output of quantum-dot thermoelectric devices, especially in inelastic systems, due to the unbounded Bose distribution at higher temperature biases.

Contribution

It demonstrates that nonlinear transport effects can enhance thermoelectric performance more effectively in inelastic quantum-dot devices than in elastic ones, revealing a new mechanism for efficiency improvement.

Findings

Nonlinear effects significantly boost efficiency and power in inelastic devices.

Enhancements are more pronounced in inelastic devices than elastic ones.

Bose distribution's unbounded nature at higher temperature biases drives the improvements.

Abstract

We study nonlinear transport effects on the maximum efficiency and power for both inelastic and elastic thermoelectric generators. The former refers to phonon-assisted hopping in double quantum-dots, while the latter is represented by elastic tunneling through a single quantum-dot. We find that nonlinear thermoelectric transport can lead to enhanced efficiency and power for both types of devices. A comprehensive survey of various quantum-dot energy, temperature, and parasitic heat conduction reveals that the nonlinear transport induced improvements of the maximum efficiency and power are overall much more significant for inelastic devices than the elastic devices, even for temperature biases as small as $T_h=1.2T_c$ ($T_h$ and $T_c$ are the temperatures of the hot and cold reservoirs, respectively). The underlying mechanism is revealed as due to the fact that, unlike the Fermi distribution, the Bose distribution is not bounded when the temperature bias increases. A large flux density of absorbed phonons leads to great enhancement of the electrical current, the output power, and the energy efficiency, dominating over the concurrent increase of the parasitic heat current. Our study reveals that nonlinear transport effects can be a useful tool for improving thermoelectric performance.