Capacitance and compressibility of heterostructures with strong electronic correlations

TL;DR

This paper investigates how strong electronic correlations and heterostructure design influence the capacitance and compressibility of layered materials, revealing non-monotonic behaviors and stability conditions relevant for electronic device engineering.

Contribution

It introduces a strong coupling evaluation of heterostructures with attractive and repulsive interactions, analyzing their capacitance and compressibility with a slave-boson technique.

Findings

Capacitance is suppressed near half-filling but enhanced near van Hove singularities.

Capacitance can vary non-monotonically with interaction strength U.

Polar dielectrics lead to smaller compressibility and increased stability.

Abstract

Strong electronic correlations related to a repulsive local interaction suppress the electronic compressibility in a single-band model, and the capacitance of a corresponding metallic film is directly related to its electronic compressibility. Both statements may be altered significantly when two extensions to the system are implemented which we investigate here: (i) we introduce an attractive nearest-neighbor interaction $V$ as antagonist to the repulsive on-site repulsion $U$, and (ii) we consider nano-structured multilayers (heterostructures) assembled from two-dimensional layers of these systems. We determine the respective total compressibility $\kappa$ and capacitance $C$ of the heterostructures within a strong coupling evaluation, which builds on a Kotliar-Ruckenstein slave-boson technique. Whereas the capacitance $C(n)$ for electronic densities $n$ close to half-filling is suppressed---illustrated by a correlation induced dip in $C(n)$---it may be appreciably enhanced close to a van Hove singularity. Moreover, we show that the capacitance may be a non-monotonic function of $U$ close to half-filling for both attractive and repulsive $V$. The compressibility $\kappa$ can differ from $C$ substantially, as $\kappa$ is very sensitive to internal electrostatic energies which in turn depend on the specific set-up of the heterostructure. In particular, we show that a capacitor with a polar dielectric has a smaller electronic compressibility and is more stable against phase separation than a standard non-polar capacitor with the same capacitance.