Effect of morphology and defectiveness of graphene-related materials on the electrical and thermal conductivity of their polymer nanocomposites

TL;DR

This study investigates how the structure and defectiveness of graphene-related nanomaterials influence the electrical and thermal conductivities of polymer nanocomposites, highlighting improvements upon defect reduction.

Contribution

It demonstrates the correlation between nanoflake defectiveness and enhanced electrical and thermal properties in polymer nanocomposites.

Findings

Reduction of nanoflake defectiveness significantly improves conductivities.

Annealed graphene oxide nanoflakes lead to higher nanocomposite performance.

Strong dependence of properties on nanoflake structure and defectiveness.

Abstract

In this work, electrically and thermally conductive poly (butylene terephthalate) nanocomposites were prepared by in-situ ring-opening polymerization of cyclic butylene terephthalate (CBT) in presence of a tin-based catalyst. One type of graphite nanoplatelets (GNP) and two different grades of reduced graphene oxide (rGO) were used. Furthermore, high temperature annealing treatment under vacuum at 1700{\deg}C was carried out on both RGO to reduce their defectiveness and study the correlation between the electrical/thermal properties of the nanocomposites and the nanoflakes structure/defectiveness. The morphology and quality of the nanomaterials were investigated by means of electron microscopy, x-ray photoelectron spectroscopy, thermogravimetry and Raman spectroscopy. Thermal, mechanical and electrical properties of the nanocomposites were investigated by means of rheology, dynamic mechanical thermal analysis, volumetric resistivity and thermal conductivity measurements. Physical properties of nanocomposites were correlated with the structure and defectiveness of nanoflakes, evidencing a strong dependence of properties on nanoflakes structure and defectiveness. In particular, a significant enhancement of both thermal and electrical conductivities was demonstrated upon the reduction of nanoflakes defectiveness.