Unusually High and Anisotropic Thermal Conductivity in Amorphous Silicon Nanostructures

TL;DR

This study reveals unexpectedly high and anisotropic in-plane thermal conductivity in amorphous silicon nanostructures, challenging previous assumptions and providing insights into vibrational mode propagation in disordered materials.

Contribution

The paper introduces novel a-Si nanostructures enabling precise in-plane thermal conductivity measurements and uncovers broad propagating vibrational mode mean free paths from 10 nm to 10 um.

Findings

In-plane k reaches ~3.0 W/m-K at 100 nm thickness.

In-plane k reaches ~5.3 W/m-K at 1.7 um thickness.

In-plane k is significantly higher than cross-plane k in the same films.

Abstract

Amorphous Si (a-Si) nanostructures are ubiquitous in numerous electronic and optoelectronic devices. Amorphous materials are considered to possess the lower limit to the thermal conductivity (k), which is ~1 W/m-K for a-Si. However, recent work suggested that k of micro-thick a-Si films can be greater than 3 W/m-K, which is contributed by propagating vibrational modes, referred to as "propagons". However, precise determination of k in a-Si has been elusive. Here, we used novel structures of a-Si nanotubes and suspended a-Si films that enabled precise in-plane k measurement within a wide thickness range of 5 nm to 1.7 um. We showed unexpectedly high in plane k in a-Si nanostructures, reaching ~3.0 and 5.3 W/m-K at 100 nm and 1.7 um, respectively. Furthermore, the measured in plane k is significantly higher than the cross-plane k on the same films. This usually high and anisotropic k in the amorphous Si nanostructures manifests the surprising broad propaganda mean free path distribution, which is found to range from 10 nm to 10 um, in the disordered and atomically isotropic structure. This result provides an unambiguous answer to the century-old problem regarding the mean free path distribution of propagons and also shed light on the design and performance of numerous a-Si based electronic and optoelectronics devices.