Atmospheric constituents and surface-level UVB: implications for a paleoaltimetry proxy and attempts to reconstruct UV exposure during volcanic episodes

TL;DR

This study uses radiative transfer modeling to explore how atmospheric constituents like ozone and aerosols influence surface UVB levels, affecting the reliability of UVB-based paleoaltitude proxies and reconstructions of past UV environments during volcanic events.

Contribution

It demonstrates that atmospheric variability can significantly impact surface UVB irradiance, highlighting the need for detailed modeling in paleoaltitude and UV environment reconstructions.

Findings

UVB irradiance varies greatly under volcanic conditions.

Altitude-related UVB changes are relatively stable across atmospheric variations.

Accurate UVB-based proxies require consistent atmospheric conditions.

Abstract

Chemical and morphological features of spores and pollens have been linked to changes in solar ultraviolet radiation (specifically UVB, 280-315 nm) at Earth's surface. Variation in UVB exposure as inferred from these features has been suggested as a proxy for paleoaltitude. While UVB irradiance does increase with altitude above sea level, a number of other factors affect the irradiance at any given place and time. In this modeling study we use the TUV atmospheric radiative transfer model to investigate dependence of surface-level UVB irradiance and relative biological impact on a number of constituents in Earth's atmosphere that are variable over long and short time periods. We consider changes in O3 column density, and SO2 and sulfate aerosols due to periods of volcanic activity, including that associated with the formation of the Siberian Traps. We find that UVB irradiance may be highly variable under volcanic conditions and variations in several of these atmospheric constituents can easily mimic or overwhelm changes in UVB irradiance due to changes in altitude. On the other hand, we find that relative change with altitude is not very sensitive to different sets of atmospheric conditions. Any paleoaltitude proxy based on UVB exposure requires confidence that the samples under comparison were located at roughly the same latitude, under very similar O3 and SO2 columns, with similar atmospheric aerosol conditions. In general, accurate estimates of the surface-level UVB exposure at any time and location require detailed radiative transfer modeling taking into account a number of atmospheric factors; this result is important for paleoaltitude proxies as well as attempts to reconstruct the UV environment through geologic time and to tie extinctions, such as the end-Permian mass extinction, to UVB irradiance changes.