On the physical limitations for radio frequency absorption in gold nanoparticle suspensions

TL;DR

This paper investigates the physical limits of radio frequency absorption in gold nanoparticle suspensions, deriving optimal conditions and using convex optimization to assess material realizability for enhanced heating.

Contribution

It introduces a conjugate match framework for maximizing absorption and explores the feasibility of passive materials to achieve this over finite bandwidths.

Findings

Optimal conjugate permittivity matches surrounding medium

Single-frequency realization via Drude model tuning

Convex optimization assesses passive material approximations

Abstract

This paper presents a study on the physical limitations for radio frequency absorption in gold nanoparticle suspensions. A canonical spherical geometry is considered consisting of a spherical suspension of colloidal gold nanoparticles characterized as an arbitrary passive dielectric material which is immersed in an arbitrary lossy medium. A relative heating coefficient and a corresponding optimal near field excitation are defined taking the skin effect of the surrounding medium into account. For small particle suspensions the optimal excitation is an electric dipole field for which explicit asymptotic expressions are readily obtained. It is then proven that the optimal permittivity function yielding a maximal absorption inside the spherical suspension is a conjugate match with respect to the surrounding lossy material. For a surrounding medium consisting of a weak electrolyte solution the optimal conjugate match can then readily be realized at a single frequency, e.g., by tuning the parameters of a Drude model corresponding to the electrophoretic particle acceleration mechanism. As such, the conjugate match can also be regarded to yield an optimal plasmonic resonance. Finally, a convex optimization approach is used to investigate the realizability of a passive material to approximate the desired conjugate match over a finite bandwidth. The relation of the proposed approach to general Mie theory as well as to the approximation of metamaterials are discussed. Numerical examples are included to illustrate the ultimate potential of heating in a realistic scenario in the microwave regime.