Magnetic instability and $f-d$ hybridization in CeFe$_2$ on substituting Cr, Ag and Au for Fe

TL;DR

This study investigates how substituting Fe with Cr, Ag, or Au affects the magnetic stability and $f-d$ hybridization in CeFe$_2$, revealing a correlation between hybridization strength and magnetic phase transitions.

Contribution

It provides direct experimental evidence linking $f-d$ hybridization variations to magnetic phase stability in CeFe$_2$ derivatives upon element substitution.

Findings

Cr induces a second magnetic transition, unlike Ag and Au.

The second transition temperature correlates with $f-d$ hybridization strength.

Cr substitution causes systematic changes in Curie and transition temperatures.

Abstract

Hybridization between Ce $f$ and conduction $d$ states has been speculatively known to be one of the mechanisms responsible for magnetic instability of the ferromagnetic ground state of CeFe$_2$. Substituting Fe by small amounts of certain elements stabilizes it to an antiferromagnetic state below the Curie temperature via a first-order second phase transition. In the present work, we seek any direct relation between the $f-d$ hybridization and the second transition by measuring primarily dc magnetization and Ce M$_{4,5}$ edge x-ray absorption spectra of Ce(Fe$_{1-x}$M$_x$)$_2$ pseudobinaries, with M = Cr, Ag and Au. X-ray diffraction and x-ray photoelectron spectroscopy measurements are also performed essentially to monitor the quality of the samples. Whereas Cr impurity is found to cause the second transition, Ag and Au apparently do not induce any. In the former, the Curie and second transition temperatures vary systematically, but differently, with $x$. Our results imply that there is a definite proportionality between the $x$ dependences of the second transition temperature and the $f-d$ hybridization strength estimated qualitatively from the absorption spectra.