Focal overlap gating in velocity map imaging to achieve high signal-to-noise ratio in photo-ion pump-probe experiments

TL;DR

This paper introduces a novel velocity map imaging technique that spatially gates the laser overlap region to significantly improve signal-to-noise ratio in pump-probe experiments, especially with high-background sources like XUV or X-rays.

Contribution

A new spatial gating method in VMI using beam tilting and timed detection enhances signal clarity by isolating the laser overlap region in pump-probe experiments.

Findings

Significant noise reduction in VMI images.

Enhanced detection of photoions from the overlap region.

Applicable to high-background XUV and X-ray experiments.

Abstract

We demonstrate a new technique in velocity map imaging (VMI) that allows spatial gating of the laser focal overlap region in time resolved pump-probe experiments. This significantly enhances signal-to-noise ratio by eliminating background signal arising outside the region of spatial overlap of pump and probe beams. This enhancement is achieved by tilting the laser beams with respect to the surface of the VMI electrodes which creates a gradient in flight time for particles born at different points along the beam. By suitably pulsing our microchannel plate detector, we can select particles born only where the laser beams overlap. This spatial gating in velocity map imaging can benefit nearly all photoion pump-probe VMI experiments especially when extreme-ultraviolet (XUV) light or X-rays are involved which produce large background signals on their own.