Mapping the nanomechanical properties of graphene suspended on silica nanoparticles

TL;DR

This study investigates the structure and elastic properties of graphene transferred onto silica nanoparticles, revealing how nanoparticle-induced rippling affects graphene's mechanical behavior and measuring its elastic modulus through AFM indentation.

Contribution

It provides new insights into the nanomechanical properties of nanoparticle-supported graphene and demonstrates a method to measure elastic modulus of suspended graphene regions.

Findings

Graphene partially follows nanoparticle morphology but remains mostly unsupported.

Suspended graphene regions can withstand forces around 10 nN.

Elastic modulus of graphene was quantified from AFM indentation measurements.

Abstract

Using nanoparticles to impart extrinsic rippling in graphene is a relatively new method to induce strain and to tailor the properties of graphene. Here we study the structure and elastic properties of graphene grown by chemical vapour deposition and transferred onto a continuous layer of SiO2 nanoparticles with diameters of around 25 nm, prepared by Langmuir-Blodgett technique on Si substrate. We show that the transferred graphene follows only roughly the morphology induced by nanoparticles. The graphene membrane parts bridging the nanoparticles are suspended and their adhesion to the AFM tip is larger compared to that of supported graphene parts. These suspended graphene regions can be deformed with forces of the order of 10 nN. The elastic modulus of graphene was determined from indentation measurements performed on suspended membrane regions with diameters in the 100 nm range.