Crystal field states of Kondo lattice heavy fermions CeRuSn3 and CeRhSn3

TL;DR

This study uses inelastic neutron scattering to determine the crystal field states of CeRuSn3 and CeRhSn3, revealing their electronic configurations, Kondo temperatures, and ground state symmetries in these heavy fermion compounds.

Contribution

First detailed crystal field level schemes for CeRuSn3 and CeRhSn3 using neutron scattering, linking electronic states to Kondo physics in these cubic heavy fermion systems.

Findings

Ce ions are in Ce3+ state at both sites.

Kondo temperatures are approximately 3.1 K and 4.6 K for CeRuSn3 and CeRhSn3.

Ground states are a quartet (cubic) and a doublet (tetragonal).

Abstract

Inelastic neutron scattering experiments have been carried out to determine the crystal field states of the Kondo lattice heavy fermions CeRuSn3 and CeRhSn3. Both the compounds crystallize in LaRuSn3-type cubic structure (space group Pm-3n) in which the Ce atoms occupy two distinct crystallographic sites with cubic (m-3) and tetragonal (-4m.2) point symmetries. The INS data of CeRuSn3 reveal the presence of a broad excitation centered around 6-8 meV which is accounted by a model based on crystal electric field (CEF) excitations. On the other hand, the INS data of isostructural CeRhSn3 reveal three CEF excitations around 7.0, 12.2 and 37.2 meV. The neutron intensity sum rule indicates that the Ce ions at both cubic and tetragonal Ce sites are in Ce3+ state in both CeRuSn3 and CeRhSn3. The CEF level schemes for both the compounds are deduced. We estimate the Kondo temperature T_K = 3.1(2) K for CeRuSn3 from neutron quasielastic linewidth in excellent agreement with that determined from the scaling of magnetoresistance which gives T_K = 3.2(1) K. For CeRhSn3 the neutron quasielastic linewidth gives T_K = 4.6 K. For both CeRuSn3 and CeRhSn3, the ground state of Ce3+ turns out to be a quartet for the cubic site and a doublet for the tetragonal site.