Moir\'e superlattices in strained graphene-gold hybrid nanostructures

TL;DR

This paper investigates how gold nanoislands induce moiré superlattices in graphene, revealing strain effects and electronic modifications, which could enable strain engineering for nanoscale electronic applications.

Contribution

It demonstrates the formation of large-wavelength moiré superlattices in graphene on gold nanoislands and explains their origin through strain-induced lattice distortion using simulations.

Findings

Moiré superlattices generate secondary Dirac points.

Large moiré periodicities are due to strain-induced lattice distortion.

Room temperature charge localization correlates with moiré patterns.

Abstract

Graphene-metal nanoparticle hybrid materials potentially display not only the unique properties of metal nanoparticles and those of graphene, but also additional novel properties due to the interaction between graphene and nanoparticles. This study shows that gold nanoislands can be used to tailor the local electronic properties of graphene. Graphene on crystalline gold nanoislands exhibits moir\'e superlattices, which generate secondary Dirac points in the local density of states. Conversely, the graphene covered gold regions undergo a polycrystalline to Au(111) phase transition upon annealing. Moreover, the nanoscale coexistence of moir\'e superlattices with different moir\'e periodicities has also been revealed. Several of these moir\'e periodicities are anomalously large, which cannot be explained by the standard lattice mismatch between the graphene and the topmost Au(111) layers. Density functional theory and molecular dynamics simulations show for the first time that in such cases the graphene and the interfacial metallic layer is strained, leading to distorted lattice constants, and consequently to reduced misfit. Room temperature charge localization induced by a large wavelength moir\'e pattern is also observed by scanning tunneling spectroscopy. These findings can open a route towards the strain engineering of graphene/metal interfaces with various moir\'e superlattices and tailored electronic properties for nanoscale information coding.