Sharp and Bright Photoluminescence Emission of Single Crystalline Diacetylene Nanoparticles

TL;DR

This study demonstrates that crystallized diacetylene nanoparticles exhibit significantly brighter and blue-shifted green photoluminescence compared to amorphous counterparts, due to enhanced molecular interactions within the nano-crystal structure.

Contribution

It introduces a method to produce highly crystalline diacetylene nanoparticles with distinct optical properties, highlighting the impact of crystallization on photoluminescence.

Findings

Crystalline DA NPs emit bright green light.

Photoluminescence peak shows blue shift in crystalline NPs.

Crystallization enhances molecular interactions affecting PL.

Abstract

Amorphous nanoparticles (NPs) of diacetylene (DA) molecules were prepared by using a reprecipitation method. After crystallization through solvent-vapor annealing process, the highly crystalline DA NPs show different structural and optical characteristics compared with the amorphous DA NPs. The single crystal structure of DA NPs was confirmed by high-resolution transmission electron microscopy (HR-TEM) and wide angle X-ray scattering (WAXS). The luminescence color and photoluminescence (PL) characteristics of the DA NPs were measured using color charge-coupled device (CCD) images and high-resolution laser confocal microscope (LCM). The crystalline DA NPs emit bright green light emission compared with amorphous DA NPs and the main PL peak of the crystalline DA NPs exhibits relative narrow and blue shift phenomena due to enhanced interaction between DA molecular in the nano-size crystal structure.