Enhancing Perovskite Electrocatalysis through Strain Tuning of the Oxygen Deficiency

TL;DR

This study demonstrates that applying epitaxial strain to perovskite thin films can effectively increase oxygen vacancies, significantly boosting catalytic activity for oxygen evolution reactions at near-room temperatures.

Contribution

The paper introduces strain engineering as a novel method to control oxygen vacancies in perovskite oxides, enhancing their catalytic performance under practical conditions.

Findings

Tensile strain induces oxygen deficiency in SrCoOx films.

Oxygen vacancies significantly improve catalytic activity, matching precious metal catalysts.

Strain controls oxygen content independently of ambient conditions.

Abstract

Oxygen vacancies in transition metal oxides facilitate catalysis critical for energy storage and generation. However, it has proven elusive to promote vacancies at the lower temperatures required for operation in devices such as metal-air batteries and portable fuel cells. Here, we use thin films of the perovskite-based strontium cobaltite (SrCoOx) to show that epitaxial strain is a powerful tool towards manipulating the oxygen content under conditions consistent with the oxygen evolution reaction, yielding increasingly oxygen deficient states in an environment where the cobaltite would normally be fully oxidized. The additional oxygen vacancies created through tensile strain enhance the cobaltite catalytic activity towards this important reaction by over an order of magnitude, equaling that of precious metal catalysts, including IrO2. Our findings demonstrate that strain in these oxides can dictate oxygen stoichiometry independent of ambient conditions, allowing unprecedented control over oxygen vacancies essential in catalysis near room temperature.