Fuel cell electrodes from organometallic Pt precursors: an easy atmospheric plasma approach

TL;DR

This paper presents a simple atmospheric plasma method to deposit platinum nanoparticles on carbon supports for fuel cell electrodes, demonstrating high efficiency and potential for practical applications.

Contribution

Introduces a novel atmospheric plasma technique for depositing platinum nanoparticles on electrode supports, offering a fast, robust, and efficient alternative to traditional methods.

Findings

High platinum content and dispersion achieved

Comparable catalytic activity to commercial electrodes

Effective at low processing temperatures

Abstract

An organometallic powder (platinum (II) acetylacetonate) is decomposed in the post-discharge of an atmospheric RF plasma torch to deposit Pt nanoparticles on carbon black supports. The resulting nanohybrid materials are characterized by FEG-SEM and XPS techniques to highlight their high content in Pt, their oxidation degree, and the dispersion of the Pt nanoparticles on the substrate. ICP-MS and electrochemical characterizations in a single fuel cell (cyclic voltammetry, dynamic polarization curves) are also performed on electrodes realized by treating the powder mixture overlaid on gas diffusion layers. The comparison of the catalytic activity and the Pt loading with commercially available electrodes shows the great potential of this simple innovative, fast, and robust deposition method.