Thermodynamically consistent Langevin dynamics with spatially correlated noise predicts frictionless regime and transient attraction effect

TL;DR

This paper develops a thermodynamically consistent Langevin dynamics framework incorporating spatially correlated noise, revealing a frictionless regime and transient attraction effects in charged particle systems, advancing understanding of non-equilibrium interactions.

Contribution

It introduces a formal expression for spatial correlations in particle-bath interactions and derives a consistent Langevin equation with spatially varying friction.

Findings

Identification of a frictionless regime in charged particle systems

Prediction of transient attraction effects due to SCN

Derivation of a spatially variant friction coefficient

Abstract

While the origin of temporal correlations in Langevin dynamics have been thoroughly researched, the understanding of Spatially Correlated Noise (SCN) is rather incomplete. In particular, very little is known about the relation between friction and SCN. In this article, we derive the formal formula for the spatial correlation function in the particle-bath interactions. This expression shows that SCN is the inherent component of binary mixtures, originating from the effective (entropic) interactions. Further, employing this spatial correlation function, we postulate the thermodynamically consistent Langevin equation driven by SCN and the adequate Fluctuation-Dissipation Relation. The thermodynamical consistency is achieved by introducing the spatially variant friction coefficient, which can be also derived analytically. This coefficient exhibits a number of intriguing properties, e.g. the singular behavior for certain interaction types. Eventually, we apply this new theory to the system of two charged particles in the presence of counter-ions. Such particles interact via the screened-charge Yukawa potential and the inclusion of SCN leads to the emergence of the anomalous frictionless regime. In this regime the particles can experience active propulsion leading to the transient attraction effect. This effect suggests a non-equilibrium mechanism facilitating the molecular binding of the like-charged particles.