Evidence of quantum Griffiths phase in Ni_{1-x}V_x nanoalloys

TL;DR

This study investigates quantum Griffiths phase in Ni-V nanoalloys, revealing non-universal power-law behaviors and signatures of QGP in nanoparticles near the critical concentration, extending understanding from bulk to nanoscale systems.

Contribution

It provides experimental evidence of quantum Griffiths phase in Ni-V nanoalloys, demonstrating its occurrence at the nanoscale and characterizing its signatures through magnetization and resistivity measurements.

Findings

Observation of non-Curie power-law susceptibility below 10 K.

Emergence of paramagnetic-like increase in magnetization below a composition-dependent temperature.

Detection of QGP signatures in nanoparticles near the critical concentration.

Abstract

Metallic Ni$_{1-x}$V$_x$ alloys are known to exhibit a ferromagnetic to paramagnetic disordered quantum phase transition (QPT) at the critical concentration $x_c \sim$ 0.114 in bulk. Such a QPT is accompanied by a quantum Griffiths phase (QGP), the physical observables in which follow non-universal power-law temperature dependences, in a finite temperature range on the paramagnetic side of the transition. In the present work, we explore the occurrence of QGP in nanoparticles of this alloy system. Nanoalloys with $x$ in the neighbourhood of $x_c$ and mean diameter 18-33 nm were prepared by a chemical reflux method. Following a few microscopic and spectroscopic studies to determine the sizes, compositions and phases, dc magnetization measurements were also performed to seek out any signature of QGP in the nanoalloys. A paramagnetic-like increase of magnetization is observed to emerge below an $x$-dependent transition temperature $\rm{T_P} (\it{x})$ within the blocked ferromagnetic state of the nanoparticles, and is corroborated by a peak at $\rm{T_P} (\it{x})$ in the temperature dependence of resistivity. The magnetic susceptibility in this emergent phase follows a non-Curie power-law temperature dependence below 10 K for $0.09 \leq x \leq 0.14$, indicating the presence of a QGP in the nanoparticles within these temperature and composition ranges.