Thermodynamic conditions during growth determine the magnetic anisotropy in epitaxial thin-films of La$_{0.7}$Sr$_{0.3}$MnO$_{3}$

TL;DR

This study shows that the magnetic anisotropy in epitaxial La$_{0.7}$Sr$_{0.3}$MnO$_{3}$ thin-films is controlled by the thermodynamic conditions during growth, affecting their suitability for magnetic device applications.

Contribution

It demonstrates that magnetic anisotropy in LSMO thin-films can be tuned by adjusting growth conditions, linking thermodynamic parameters to magnetic properties.

Findings

PLD films exhibit in-plane cubic and uniaxial anisotropy with perpendicular anisotropy.

CSD films show suppressed uniaxial and reduced out-of-plane anisotropy, with stronger in-plane cubic anisotropy.

Growth conditions influence MnO$_{6}$ octahedral rotation patterns, affecting magnetic anisotropy.

Abstract

The suitability of a particular material for use in magnetic devices is determined by the process of magnetization reversal/relaxation, which in turn depends on the magnetic anisotropy. Therefore, designing new ways to control magnetic anisotropy in technologically important materials is highly desirable. Here we show that magnetic anisotropy of epitaxial thin-films of half-metallic ferromagnet La$_{0.7}$Sr$_{0.3}$MnO$_{3}$ (LSMO) is determined by the proximity to thermodynamic equilibrium conditions during growth. We performed a series of X-ray diffraction and ferromagnetic resonance (FMR) experiments in two different sets of samples: the first corresponds to LSMO thin-films deposited under tensile strain on (001) SrTiO$_{3}$ by Pulsed Laser Deposition (PLD; far from thermodynamic equilibrium); the second were deposited by a slow Chemical Solution Deposition (CSD) method, under quasi-equilibrium conditions. Thin films prepared by PLD show a in-plane cubic anisotropy with an overimposed uniaxial term. A large anisotropy constant perpendicular to the film plane was also observed in these films. However, the uniaxial anisotropy is completely suppressed in the CSD films. The out of plane anisotropy is also reduced, resulting in a much stronger in plane cubic anisotropy in the chemically synthesized films. This change is due to a different rotation pattern of MnO$_{6}$ octahedra to accomodate epitaxial strain, which depends not only on the amount of tensile stress imposed by the STO substrate, but also on the growth conditions. Our results demonstrate that the nature and magnitude of the magnetic anisotropy in LSMO can be tuned by the thermodynamic parameters during thin-film deposition.