Structural and magnetic properties of S = 3/2 chemically disordered perovskite Sr2TiMnO6

TL;DR

This study synthesizes and characterizes the disordered perovskite Sr2TiMnO6, revealing a canted antiferromagnetic state around 13K and potential magneto-dielectric coupling, with detailed structural and physical property analysis.

Contribution

It provides the first detailed structural and magnetic characterization of chemically disordered Sr2TiMnO6, identifying its true disordered perovskite structure and magnetic properties.

Findings

Disordered perovskite structure with Pm-3m space group

Canted antiferromagnetic ordering around 13K

Possible magneto-dielectric coupling near 14K

Abstract

Single phase polycrystalline sample of perovskite Sr2TiMnO6 (STMO) has been successfully synthesized via solid state reaction route. Its detailed structural and physical properties have been studied using x-ray diffraction, transmission electron microscopy, magnetization, specific heat, and dielectric measurements. Rietveld analysis of the powder XRD data and transmission electron microscopy studies confirm that STMO is not a double perovskite structure with Fm-3m space group. But it is a disordered perovskite structure with Pm-3m space group where Ti4+ and Mn4+ ions are randomly distributed at the 1b site. The dc magnetization (\c{hi}dc-vs-T) measurements in the temperature range 2-300K reveals a single anomaly at ~13K with predominant long range canted antiferromagnetic (AFM) ordering. The frequency invariant maxima at 13K in the ac susceptibility (\c{hi}ac-vs-T) discards the spin-glass behaviour in STMO. Despite the presence of sharp feature in M-T data, the specific heat data (Cp-vs-T) shows only a broad hump around 13K, which has been attributed to the magneto-structural ordering giving rise to canted AFM state in chemically disorder STMO. Matching with the magnetic and specific heat anomaly, the dielectric permittivity also shows a broad anomaly around 14K, indicating the possible magneto-dielectric coupling in STMO.