Superelastic softening of ferroelastic multidomain crystals

TL;DR

This paper investigates the giant elastic softening in ferroelastic materials caused by domain wall motion, introduces a new Landau-Ginzburg model to describe superelastic softening, and applies it to both improper and proper ferroelastic systems.

Contribution

It presents a novel theoretical model based on Landau-Ginzburg theory that accurately describes superelastic softening in ferroelastic materials, extending previous understanding.

Findings

The model explains superelastic softening in perovskites.

Elastic softening can be suppressed with uniaxial stress.

Application to La1-xNdxP5O14 demonstrates model's versatility.

Abstract

Many proper and improper ferroelastic materials display (at sufficiently low measurement frequencies) a huge elastic softening below Tc. This giant elastic softening, which can be suppressed with uniaxial stress, is caused by domain wall motion. Here we shortly review our results on frequency and temperature dependent elastic measurements of some perovskites which exhibit improper ferroelastic phase transitions. We also present a new model - based on Landau-Ginzburg theory including long range interaction of needle shaped ferroelastic domains - which describes superelastic softening observed in some of the perovskite systems very well. We also show, howthe theory can be extended to describe proper ferroelastic materials and apply the theory to describe the elastic behaviour of the proper ferroelastic material La1-xNdxP5O14 (LNPP).