Magnetic and Thermal Properties of SmRh$_2$Zn$_{20}$ Single Crystal

TL;DR

This study investigates the magnetic and thermal properties of SmRh$_2$Zn$_{20}$ single crystals, revealing antiferromagnetic behavior, valence stability, and field-dependent magnetic transitions, supported by theoretical modeling.

Contribution

The paper provides a comprehensive experimental and theoretical analysis of SmRh$_2$Zn$_{20}$, highlighting its antiferromagnetic order, valence state, and magnetic field effects, which are novel insights for this compound.

Findings

Sm ions are trivalent with no valence fluctuations.

SmRh$_2$Zn$_{20}$ exhibits antiferromagnetic order at 2.46 K.

Magnetic field influences the Néel temperature and magnetic structure.

Abstract

The magnetization, magnetic susceptibility, and specific heat of the single crystalline sample SmRh$_2$Zn$_{20}$ were measured. The valence of Sm ions in SmRh$_2$Zn$_{20}$ was found to be trivalent. No evidence of valence fluctuations was detected. SmRh$_2$Zn$_{20}$ is an antiferromagnet with $T_{\rm N}=$ 2.46 K. The observed $C(T,H)$ curves showed that $T_{\rm N}$ splits into two in the external field $H$ along the [001] and [101]directions. On the other hand, $T_{\rm N}$ in $H$ along the [111] direction did not split, decreasing to 2.20 K at $H=7$ T. At 2 K, the magnetization $M_{111}$ in $H$ along the [111] direction increased linearly with increasing field, while $M_{001}$ and $M_{101}$ deviated upward slightly from the linear dependence. We analyzed the observed magnetic and thermal properties of SmRh$_2$Zn$_{20}$ taking into account the crystalline-electric-field effect, the Zeeman energy, and the exchange interaction. The theoretical calculation well reproduced the experimental $\chi(T)$, $M(H)$, $C(T,H)$ and $T_{\rm N}(H)$. The sublattice magnetic moments are expected to be along the $\langle 111\rangle$ direction below $T_{\rm N}$ at $H=0$ T. Variations of the magnetic structures induced by the external magnetic fields in a narrow temperature region around $T_{\rm N}$ are inferred on the basis of theoretical calculations.