Universal bounds on current fluctuations

TL;DR

This paper establishes four universal bounds on current fluctuations in non-equilibrium steady states of Markovian processes, applicable beyond Gaussian regimes, and provides insights into their tightness and conditions of validity.

Contribution

It introduces four new universal bounds on current fluctuations, including a proven exponential bound and conjectured bounds, expanding understanding of fluctuation constraints in non-equilibrium systems.

Findings

A universal parabolic bound depends only on average entropy production.

An exponential bound is rigorously proved and often tighter than the parabolic bound.

The bounds are applicable to various driven diffusive systems and provide new constraints for nonequilibrium systems.

Abstract

For current fluctuations in non-equilibrium steady states of Markovian processes, we derive four different universal bounds valid beyond the Gaussian regime. Different variants of these bounds apply to either the entropy change or any individual current, e.g., the rate of substrate consumption in a chemical reaction or the electron current in an electronic device. The bounds vary with respect to their degree of universality and tightness. A universal parabolic bound on the generating function of an arbitrary current depends solely on the average entropy production. A second, stronger bound requires knowledge both of the thermodynamic forces that drive the system and of the topology of the network of states. These two bounds are conjectures based on extensive numerics. An exponential bound that depends only on the average entropy production and the average number of transitions per time is rigorously proved. This bound has no obvious relation to the parabolic bound but it is typically tighter further away from equilibrium. An asymptotic bound that depends on the specific transition rates and becomes tight for large fluctuations is also derived. This bound allows for the prediction of the asymptotic growth of the generating function. Even though our results are restricted to networks with a finite number of states, we show that the parabolic bound is also valid for three paradigmatic examples of driven diffusive systems for which the generating function can be calculated using the additivity principle. Our bounds provide a new general class of constraints for nonequilibrium systems.