Polaronic effects in monolayer black phosphorus on polar substrates

TL;DR

This paper studies how substrate-induced polaronic effects alter the electronic band gap and effective masses in monolayer black phosphorus, revealing substrate-dependent modifications that influence its electronic properties.

Contribution

It introduces an analytical approach based on Lee-Low-Pines theory to quantify substrate-related polaronic effects on black phosphorus's band structure.

Findings

Energy gap increases by up to 50 meV depending on substrate and distance

Effective masses are renormalized, especially along the zigzag direction

Polaronic effects enhance anisotropy in effective masses

Abstract

We investigate the effect of charge carrier interaction with surface optical phonons on the band properties of monolayer black phosphorus induced by polar substrates. We develop an analytical method based on the Lee-Low-Pines theory to calculate the spectrum of Fr\"ohlich type continuum Hamiltonian in the long-wavelength limit. We examine the modification of a band gap and renormalization of effective masses due to the substrate-related polaronic effect. Our results show that an energy gap in supported monolayer black phosphorus is enlarged depending on a particular substrate and the interlayer distance, $z$. Among the substrate considered, the largest gap broadening at $ z=2.5$ \AA{} is observed for the Al$_{2} $O$_{3} $ substrate, which is found to be $ \sim 50$ meV. Carrier-phonon coupling also renormalizes the effective masses which is more pronounced along the zigzag direction. Anisotropy of the effective masses becomes stronger by the influence of the polaronic effect corresponding to direction-dependent carrier-phonon coupling. We conclude that substrate phonons have a non-negligible effect on the static band properties of monolayer black phosphorus, which may be further exploited in its experimental and theoretical studies.