Controlling Gaussian and mean curvatures at microscale by sublimation and condensation of smectic liquid crystals

TL;DR

This paper demonstrates how sublimation and condensation processes can be used to precisely control the Gaussian and mean curvatures of smectic liquid crystal films at microscale, enabling novel soft morphologies.

Contribution

It introduces a method to manipulate the curvature of smectic films through sintering, revealing new structures with positive Gaussian curvature not achievable by cooling.

Findings

Sublimation and condensation reshape initial smectic films into highly curved structures.

The curvature pattern influences sublimation rates and resulting morphologies.

New positive Gaussian curvature structures are observed, expanding the design space for soft materials.

Abstract

Soft materials with layered structure such as membranes, block copolymers, and smectics exhibit intriguing morphologies with nontrivial curvatures. We report on restructuring the Gaussian and mean curvatures of smectic A films with free surface in the process of sintering, i.e. reshaping at elevated temperatures. The pattern of alternating patches of negative, zero, and positive mean curvature of the air-smectic interface has a profound effect on the rate of sublimation. As a result of sublimation, condensation, and restructuring, initially equilibrium smectic films with negative and zero Gaussian curvature are transformed into structures with pronounced positive Gaussian curvature of layers packing, seldom seen in samples obtained by cooling from the isotropic melt. The observed relationship between the curvatures, bulk elastic behaviour, and interfacial geometries in sintering of smectic liquid crystals paves the way for new approaches to control soft morphologies at micron and submicron scales.