Photocell Optimisation Using Dark State Protection

TL;DR

This paper proposes a novel method to surpass the efficiency limit of traditional photocells by utilizing dark states arising from dipole interactions in molecular dimers, enhancing light-to-current conversion.

Contribution

It introduces a model showing how dark states in molecular dimers can improve photocell efficiency and provides a screening roadmap for suitable molecules.

Findings

Dark states naturally occur in molecular dimers due to dipole interactions.

Asymmetric dimers significantly enhance light-to-current conversion.

A practical screening method for candidate molecules is proposed.

Abstract

Conventional photocells suffer a fundamental efficiency threshold imposed by the principle of detailed balance, reflecting the fact that good absorbers must necessarily also be fast emitters. This limitation can be overcome by `parking' the energy of an absorbed photon in a dark state which neither absorbs nor emits light. Here we argue that suitable dark states occur naturally as a consequence of the dipole-dipole interaction between two proximal optical dipoles for a wide range of realistic molecular dimers. We develop an intuitive model of a photocell comprising two light-absorbing molecules coupled to an idealised reaction centre, showing asymmetric dimers are capable of providing a significant enhancement of light-to-current conversion under ambient conditions. We conclude by describing a roadmap for identifying suitable molecular dimers for demonstrating this effect by screening a very large set of possible candidate molecules.