Luminescence of photochromic centers in calcium fluoride crystals doped with Lu$^{3+}$ ions
Roman Shendrik, Alexandra Myasnikova, Tatiana Sizova, Evgeny, Radzhabov

TL;DR
This study investigates the luminescence properties of photochromic centers in calcium fluoride crystals doped with lutetium ions, combining experimental spectra analysis with ab initio calculations to understand their optical behavior.
Contribution
It provides new experimental data and theoretical calculations on the luminescence spectra of photochromic centers in Lu-doped calcium fluoride crystals.
Findings
Luminescence spectra linked to photochromic centers identified.
Ab initio calculations agree with experimental absorption spectra.
Irradiation induces specific emission transitions.
Abstract
We report data on the luminescence spectra associated with photochromic centers in X-ray irradiated calcium fluoride crystals doped with Lu ions. Irradiation in low energy photochromic centers absorption band excites emission, which can be identify with transitions into photochromic centers. Ab initio calculation of absorption spectrum of photochromic center agrees rather well with experimental data.
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