Spectroscopy and perturbation analysis of the CO A$^1\Pi-$X$^1\Sigma^+$ (2,0), (3,0) and (4,0) bands

TL;DR

This study used high-resolution vacuum ultraviolet spectroscopy combined with laser data to analyze the perturbations in the CO A$^1\Pi$-$X^1\Sigma^+$ system across multiple vibrational bands, achieving high accuracy in spectral line measurements.

Contribution

It provides a highly accurate re-investigation of CO's A$^1\\Pi$-$X^1\\Sigma^+$ bands, including perturbation analysis with improved spectral data and accuracy.

Findings

Rotational levels up to J=52 observed.

Perturbations analyzed in multiple vibrational levels.

High-precision spectral line data obtained.

Abstract

The (2,0) (3,0) and (4,0) bands of the A$^1\Pi-$X$^1\Sigma^+$ system of $^{12}$C$^{16}$O have been re-investigated by high-resolution vacuum ultraviolet absorption spectroscopy. A VUV Fourier-transform spectrometer, illuminated by synchrotron radiation, was applied to record a jet-cooled spectrum, a room temperature static gas spectrum and a high temperature (900 K) quasi-static gas spectrum, resulting in absolute accuracies of 0.01$-$0.02 cm$^{-1}$ for the rotational line frequencies. Precise laser-based data were included in the analysis allowing for a highly accurate determination of band origins. Rotational levels up to $J=52$ were observed. The data were used to perform an improved analysis of the perturbations in the A$^1\Pi$, $v=2$, $v=3$, and $v=4$ levels by vibrational levels of the D$^1\Delta$, I$^1\Sigma^-$, e$^3\Sigma^-$, d$^3\Delta$, and a$'^3\Sigma^+$ states.