The role of volatiles in reactive melt transport in the asthenosphere

TL;DR

This study develops a novel computational framework to show that small amounts of volatiles like water and CO2 significantly influence melt transport and reactive channel formation in the upper mantle, affecting magma generation and dynamics.

Contribution

It introduces a new thermodynamically consistent method for simulating volatile-rich mantle melting and demonstrates reactive channeling caused by deep, volatile-rich melts.

Findings

Volatile-rich melts cause reactive channelisation at depths near the solidus.

Segregation of deep volatiles promotes reactive instability and fast melt pathways.

Water and CO2 significantly influence magma genesis and melt transport dynamics.

Abstract

Experimental studies of mantle petrology find that small concentrations of water and carbon dioxide have a large effect on the solidus temperature and distribution of melting in the upper mantle. However, it has remained unclear what effect small fractions of deep, volatile-rich melts have on melt transport and reactive melting in the shallow asthenosphere. Here we present theory and computations indicating that low-degree, reactive, volatile-rich melts cause channelisation of magmatic flow at depths approximately corresponding to the anhydrous solidus temperature. These results are obtained with a novel method to simulate the thermochemical evolution of the upper mantle in the presence of volatiles. The method uses a thermodynamically consistent framework for reactive, disequilibrium, multi-component melting. It is coupled with a system of equations representing conservation of mass, momentum, and energy for a partially molten grain aggregate. Application of this method in two-phase, three-component upwelling-column models demonstrates that it reproduces leading-order features of hydrated and carbonated peridotite melting; in particular, it captures the production of low-degree, volatile-rich melt at depths far below the volatile-free solidus. The models predict that segregation of volatile-rich, deep melts promotes a reactive channeling instability that creates fast and chemically isolated pathways of melt extraction. Reactive channeling occurs where volatile-rich melts flux the base of the silicate melting region, enhancing dissolution of fusible components from the ambient mantle. We find this effect to be similarly expressed for models of both hydrated and carbonated mantle melting. These findings indicate that despite their small concentrations, water and carbon dioxide have an important control on the extent and style of magma genesis, as well as on the dynamics of melt transport.