Detection of extragalactic argonium, ArH$^+$, toward PKS~1830$-$211
Holger S.P. M\"uller, S\'ebastien Muller, Peter Schilke, Edwin A., Bergin, John H. Black, Maryvonne Gerin, Dariusz C. Lis, David A. Neufeld, and, S\"umeyye Suri

TL;DR
This study reports the first detection of argonium (ArH+) in an extragalactic source, demonstrating its potential as a tracer of diffuse atomic interstellar medium and providing insights into cosmic ray ionization and nucleosynthesis at high redshift.
Contribution
First extragalactic detection of ArH+ using ALMA, establishing its role as a tracer of diffuse atomic ISM in distant galaxies and analyzing isotopic ratios for nucleosynthesis insights.
Findings
ArH+ detected in absorption toward PKS 1830-211
Argonium absorption is stronger in more diffuse regions
Isotopic ratio 36Ar/38Ar is lower than solar value
Abstract
Argonium has recently been detected as a ubiquitous molecule in our Galaxy. Model calculations indicate that its abundance peaks at molecular fractions in the range of 1E-4 to 1E-3 and that the observed column densities require high values of the cosmic ray ionization rate. Therefore, this molecular cation may serve as an excellent tracer of the very diffuse interstellar medium (ISM), as well as an indicator of the cosmic ray ionization rate. We attempted to detect ArH+ in extragalactic sources to evaluate its diagnostic power as a tracer of the almost purely atomic ISM in distant galaxies. We obtained ALMA observations of a foreground galaxy at z = 0.89 in the direction of the lensed blazar PKS 1830-211. Two isotopologs of argonium, 36ArH+ and 38ArH+, were detected in absorption along two different lines of sight toward PKS 1830-211, known as the SW and NE images of the background…
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