Spin-orbital excitation continuum and anomalous electron-phonon interaction in the Mott insulator LaTiO$_3$

TL;DR

This study reveals a temperature-dependent electronic continuum and phonon interactions in LaTiO₃, highlighting liquid-like spin and orbital correlations in this Mott insulator through Raman scattering.

Contribution

It uncovers the evolution of electronic and phononic excitations across the magnetic transition, demonstrating strong spin-orbital coupling effects in LaTiO₃.

Findings

Electronic continuum develops a gap below T_N

Pronounced Fano anomalies in phonons above T_N

Unusual renormalization of phonon lifetime with magnetic order

Abstract

Raman scattering experiments on stoichiometric, Mott-insulating LaTiO$_3$ over a wide range of excitation energies reveal a broad electronic continuum which is featureless in the paramagnetic state, but develops a gap of $\sim 800$ cm$^{-1}$ upon cooling below the N\'eel temperature $T_N = 146$ K. In the antiferromagnetic state, the spectral weight below the gap is transferred to well-defined spectral features due to spin and orbital excitations. Low-energy phonons exhibit pronounced Fano anomalies indicative of strong interaction with the electron system for $T > T_N$, but become sharp and symmetric for $T < T_N$. The electronic continuum and the marked renormalization of the phonon lifetime by the onset of magnetic order are highly unusual for Mott insulators and indicate liquid-like correlations between spins and orbitals.