Plasmonic and silicon spherical nanoparticle anti-reflective coatings

TL;DR

This study compares plasmonic and all-dielectric nanoparticle coatings for anti-reflective applications, revealing mechanisms behind zero reflection and demonstrating enhanced light absorption in photovoltaic devices.

Contribution

It introduces the substrate-mediated Kerker effect in silicon coatings and compares the anti-reflective performance of silicon and silver nanoparticle coatings.

Findings

Silicon coatings achieve zero reflection via interference of dipole responses.

Silver coatings exhibit substrate-induced bi-anisotropy and blooming effects.

Coatings can increase light absorption in photovoltaic cells by up to 30%.

Abstract

Over the last decade, plasmonic antireflecting nanostructures have been extensively studied to be utilized in various optical and optoelectronic systems such as lenses, solar cells, photodetectors, and others. The growing interest to all-dielectric photonics as an alternative optical technology along with plasmonics motivates us to compare antireflection properties of all-dielectric and plasmonic nanoparticle coatings based on silver and crystalline silicon. Our results of numerical simulations for periodic arrays of spherical nanoparticles on top of amorphous silicon show that both silicon and silver nanoparticle coatings demonstrate strong anti-reflective properties in the visible spectral range. In this work, we show for the first time that blooming effect, that is zero reflection from the structure, with silicon coatings originates from the interference of electric- and magnetic-dipole responses of nanoparticles with the wave reflected from the substrate, and we refer to it as substrate-mediated Kerker effect. For the silver coating, our results agree with previously observed substrate-induced bi-anisotropy and blooming, caused by substrate-induced magnetic response. Finally, we numerically show high effectiveness of silicon and silver coatings for the application in thin-film photovoltaic elements, which is related to the suppression of reflection from the high-index substrate and increased light absorbance in the active layer with coating. Depending on the nanoparticle size, either silicon or silver coating is more efficient, and overall increase of absorption up to 30% can be achieved.