40Ar/39Ar ages of lunar impact glasses: Relationships among Ar diffusivity, chemical composition, shape, and size

TL;DR

This study analyzes 73 lunar impact glasses to understand how size, shape, and composition affect argon retention and age determination, revealing insights into lunar impact history and glass preservation over time.

Contribution

It establishes relationships among Ar diffusivity, chemical composition, shape, and size, providing criteria for selecting reliable lunar impact glass ages.

Findings

Larger, chemically suitable glasses retain more radiogenic Ar.

Approximately 50% of glasses are younger than 500 Ma.

Age distribution reflects preservation bias and lunar impact history.

Abstract

Lunar impact glasses, quenched melts produced during cratering events on the Moon, have the potential to provide not only compositional information about both the local and regional geology of the Moon but also information about the impact flux over time. We present in this paper the results of 73 new 40Ar/39Ar analyses of well-characterized, inclusion-free lunar impact glasses and demonstrate that size, shape, chemical composition, fraction of radiogenic 40Ar retained, and cosmic ray exposure (CRE) ages are important for 40Ar/39Ar investigations of these samples. Specifically, analyses of lunar impact glasses from the Apollo 14, 16, and 17 landing sites indicate that retention of radiogenic 40Ar is a strong function of post-formation thermal history in the lunar regolith, size, and chemical composition. Based on the relationships presented in this paper, lunar impact glasses with compositions and sizes sufficient to have retained 90% of their radiogenic Ar during 750 Ma of cosmic ray exposure at time-integrated temperatures of up to 290 K have been identified and are likely to have yielded reliable 40Ar/39Ar ages of formation. Additionally, ~50% of the identified impact glass spheres have formation ages of <500 Ma, while ~75% of the identified lunar impact glass shards and spheres have ages of formation <2000 Ma. The observed age-frequency distribution of lunar impact glasses may reflect two processes: (i) diminished preservation due to spontaneous shattering with age; and (ii) preservation of a remnant population of impact glasses from the tail end of the terminal lunar bombardment having 40Ar/39Ar ages up to 3800 Ma. A protocol is described for selecting and analyzing lunar impact glasses.