Singular perturbations approach to localized surface-plasmon resonance: Nearly touching metal nanospheres

TL;DR

This paper develops a singular perturbation method to analyze localized surface-plasmon resonance in nearly touching metal nanospheres, providing explicit formulas for resonance conditions and field enhancements.

Contribution

It introduces an asymptotic approach to model plasmonic resonances in complex nano-structures, offering analytical solutions where exact methods are difficult.

Findings

Derived closed-form resonance conditions for metal dielectric function

Provided explicit formulas for induced dipole moments and field enhancements

Validated asymptotic results with semi-numerical computations

Abstract

Metallic nano-structures characterised by multiple geometric length scales support low-frequency surface-plasmon modes, which enable strong light localization and field enhancement. We suggest studying such configurations using singular perturbation methods, and demonstrate the efficacy of this approach by considering, in the quasi-static limit, a pair of nearly touching metallic nano-spheres subjected to an incident electromagnetic wave polarized with the electric field along the line of sphere centers. Rather than attempting an exact analytical solution, we construct the pertinent (longitudinal) eigen-modes by matching relatively simple asymptotic expansions valid in overlapping spatial domains. We thereby arrive at an effective boundary eigenvalue problem in a half-space representing the metal region in the vicinity of the gap. Coupling with the gap field gives rise to a mixed-type boundary condition with varying coefficients, whereas coupling with the particle-scale field enters through an integral eigenvalue selection rule involving the electrostatic capacitance of the configuration. By solving the reduced problem we obtain accurate closed-form expressions for the resonance values of the metal dielectric function. Furthermore, together with an energy-like integral relation, the latter eigen-solutions yield also closed-form approximations for the induced-dipole moment and gap-field enhancement under resonance. We demonstrate agreement between the asymptotic formulas and a semi-numerical computation. The analysis, underpinned by asymptotic scaling arguments, elucidates how metal polarization together with geometrical confinement enables a strong plasmon-frequency redshift and amplified near-field at resonance.