Tuning bad metal and non-Fermi liquid behavior in a Mott material: rare earth nickelate thin films

TL;DR

This study investigates how strain influences bad metal and non-Fermi liquid behaviors in NdNiO3 thin films, revealing that orbital splitting controls resistance saturation and phase crossover, aiding in orbital engineering for novel devices.

Contribution

It demonstrates that strain-induced orbital splitting governs bad metal and non-Fermi liquid phases in NdNiO3, providing a predictive criterion for strong localization and phase behavior.

Findings

Resistance saturation depends on Ni eg orbital splitting.

Strain tuning induces bad metal behavior in NdNiO3.

Phase crossover is linked to orbital engineering.

Abstract

Resistances that exceed the Mott-Ioffe-Regel limit, known as bad metal behavior, and non-Fermi liquid behavior are ubiquitous features of the normal state of many strongly correlated materials. Here we establish the conditions that lead to bad metal and non-Fermi liquid phases in NdNiO3, which exhibits a prototype, bandwidth-controlled metal-insulator transition. We show that resistance saturation is determined by the magnitude of the Ni eg orbital splitting, which can be tuned by strain in epitaxial films, causing the appearance of bad metal behavior under certain conditions. The results shed light on the nature of a crossover to non-Fermi liquid metal phase and provide a predictive criterion for strong localization. They elucidate a seemingly complex phase behavior as a function of film strain and confinement and provide guidelines for orbital engineering and novel devices.