A Spectral Analysis of Laser Induced Fluorescence of Iodine

TL;DR

This paper presents a spectral analysis of laser-induced fluorescence in iodine, demonstrating a straightforward experimental setup for studying molecular energy structures and vibrational states suitable for educational purposes.

Contribution

It introduces an inexpensive experimental method and spectral analysis technique for studying iodine's energy structure, ideal for advanced laboratory courses.

Findings

Successful assignment of spectral lines

Estimation of vibrational constants

Discussion of molecular vibrational models

Abstract

When optically excited, iodine absorbs in the 490- to 650-nm visible region of the spectrum and, after radiative relaxation, it displays an emission spectrum of discrete vibrational bands at moderate resolution. This makes laser-induced fuorescence spectrum of molecular iodine especially suitable to study the energy structure of homonuclear diatomic molecules at room temperature. In this spirit, we present a rather straightforward and inexpensive experimental setup and the associated spectral analysis which provides an excellent exercise of applied quantum mechanics fit for advanced laboratory courses. The students would be required to assign spectral lines, fill a Deslandres table, process the data to estimate the harmonic and anharmonic characteristics of the ground vibronic state involved in the radiative transitions, and thenceforth calculate a set of molecular constants and discuss a model of molecular vibrator.