Control of atomic transition rates via laser light shaping

TL;DR

This paper systematically analyzes how shaping external laser light fields can modify atomic transition rates, considering various structured light sources and their effects on internal and center of mass atomic states.

Contribution

It provides a comprehensive formalism for controlling atomic transition rates through tailored electromagnetic fields, including analytical comparisons of different structured light modes.

Findings

Gaussian and Laguerre-Gaussian beams can significantly enhance transition rates with small waists.

Propagation invariant modes like Bessel and Weber beams can maximize transition rate enhancements.

Control over both atomic states and electromagnetic field shaping is essential for effective transition manipulation.

Abstract

A modular systematic analysis of the feasibility of modifying atomic transition rates by tailoring the electromagnetic field of an external coherent light source is presented. The formalism considers both the center of mass and internal degrees of freedom of the atom, and all properties of the field: frequency, angular spectrum, and polarization. General features of recoil effects for internal forbidden transitions are discussed. A comparative analysis of different structured light sources is explicitly worked out. It includes spherical waves, Gaussian beams, Laguerre-Gaussian beams, and propagation invariant beams with closed analytical expressions. It is shown that increments in the order of magnitude of the transition rates for Gaussian and Laguerre-Gaussian beams, with respect to those obtained in the paraxial limit, requires waists of the order of the wavelength, while propagation invariant modes may considerably enhance transition rates under more favorable conditions. For transitions that can be naturally described as modifications of the atomic angular momentum, this enhancement is maximal (within propagation invariant beams) for Bessel modes, Mathieu modes can be used to entangle the internal and center of mass involved states, and Weber beams suppress this kind of transitions unless they have a significant component of odd modes. However, if a recoil effect of the transition with an adequate symmetry is allowed, the global transition rate (center of mass and internal motion) can also be enhanced using Weber modes. The global analysis presented reinforces the idea that a better control of the transitions between internal atomic states requires both a proper control of the available states of the atomic center of mass, and shaping of the background electromagnetic field.