The Keck+Magellan Survey for Lyman Limit Absorption III: Sample Definition and Column Density Measurements
J. Xavier Prochaska (1), John M. O'Meara (2), Michele Fumagalli (3,4),, Rebecca A. Bernstein (4), Scott M. Burles (5) ((1) UCO/Lick, University of, California, Santa Cruz, (2) Saint Michael's College, (3) Durham University,

TL;DR
This survey of 157 Lyman Limit Systems at high redshift measures hydrogen and metal-line column densities, revealing high ionization, metallicity dispersion, and metal enrichment over cosmic time, with implications for galaxy evolution.
Contribution
It provides new high-resolution measurements of NHI and metal lines in LLSs, expanding understanding of their ionization states and metallicities at z=1.76-4.39.
Findings
Most LLSs are highly ionized.
Large metallicity dispersion among LLSs.
Heavy element pollution increases with redshift.
Abstract
We present an absorption-line survey of optically thick gas clouds -- Lyman Limit Systems (LLSs) -- observed at high dispersion with spectrometers on the Keck and Magellan telescopes. We measure column densities of neutral hydrogen NHI and associated metal-line transitions for 157 LLSs at z=1.76-4.39 restricted to 10^17.3 < NHI < 10^20.3. An empirical analysis of ionic ratios indicates an increasing ionization state of the gas with decreasing NHI and that the majority of LLSs are highly ionized, confirming previous expectations. The Si^+/H^0 ratio spans nearly four orders-of-magnitude, implying a large dispersion in the gas metallicity. Fewer than 5% of these LLSs have no positive detection of a metal transition; by z~3, nearly all gas that is dense enough to exhibit a very high Lyman limit opacity has previously been polluted by heavy elements. We add new measurements to the small…
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