Single Gate P-N Junctions in Graphene-Ferroelectric Devices
J. Henry Hinnefeld, Ruijuan Xu, Steven Rogers, Shishir Pandya, Moonsub, Shim, Lane W. Martin, Nadya Mason

TL;DR
This paper demonstrates a method to create and control graphene p-n junctions using a ferroelectric substrate and environmental doping, enabling on-demand switching with a single gate.
Contribution
It introduces a simple fabrication technique for graphene p-n junctions with ferroelectric substrates and demonstrates their controllable, hysteresis-based switching behavior.
Findings
P-n junctions can be formed via substrate modifications and environmental doping.
The ferroelectric substrate induces hysteresis in doping levels.
A single backgate can control the activation and deactivation of the p-n junctions.
Abstract
Graphene's linear dispersion relation and the attendant implications for bipolar electronics applications have motivated a range of experimental efforts aimed at producing p-n junctions in graphene. Here we report electrical transport measurements of graphene p-n junctions formed via simple modifications to a PbZrTiO substrate, combined with a self-assembled layer of ambient environmental dopants. We show that the substrate configuration controls the local doping region, and that the p-n junction behavior can be controlled with a single gate. Finally, we show that the ferroelectric substrate induces a hysteresis in the environmental doping which can be utilized to activate and deactivate the doping, yielding an `on-demand' p-n junction in graphene controlled by a single, universal backgate.
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