Relation between $c$-$f$ hybridization and magnetic ordering in CeRu$_2$Al$_{10}$: An optical conductivity study of Ce(Ru$_{1-x}$Rh$_x$)$_2$Al$_{10}$ ($x\leq0.05$)

TL;DR

This study investigates how $c$-$f$ hybridization influences magnetic ordering in CeRu$_2$Al$_{10}$ and its Rh-doped variants, revealing that magnetic moment direction change correlates with hybridization suppression, while ordering temperature relates to charge excitations.

Contribution

It provides new insights into the relationship between $c$-$f$ hybridization and magnetic properties in CeRu$_2$Al$_{10}$ through optical conductivity measurements and doping analysis.

Findings

$c$-$f$ hybridization gap is observed at 40 meV along all axes.

The 20 meV peak appears only along the $b$ axis and remains strong with doping.

Magnetic moment direction changes from $c$ to $a$ axis as hybridization weakens.

Abstract

A Kondo semiconductor CeRu$_2$Al$_{10}$ with an orthorhombic crystal structure shows an unusual antiferromagnetic ordering at rather high temperature $T_0$ of 27.3 K, which is lower than the Kondo temperature $T_{\rm K}\sim$ 60 K. In optical conductivity [$\sigma(\omega)$] spectra that directly reflect electronic structure, the $c$-$f$ hybridization gap between the conduction and $4f$ states is observed at around 40 meV along the three principal axes. However, an additional peak at around 20 meV appears only along the $b$ axis. With increasing $x$ to 0.05 in Ce(Ru$_{1-x}$Rh$_x$)$_2$Al$_{10}$, the $T_0$ decreases slightly from 27.3 K to 24 K, but the direction of the magnetic moment changes from the $c$ axis to the $a$ axis. Thereby, the $c$-$f$ hybridization gap in the $\sigma(\omega)$ spectra is strongly suppressed, but the intensity of the 20-meV peak remains as strong as for $x=0$. These results suggest that the change of the magnetic moment direction originates from the decreasing of the $c$-$f$ hybridization intensity. The magnetic ordering temperature $T_0$ is not directly related to the $c$-$f$ hybridization but is related to the charge excitation at 20 meV observed along the $b$ axis.