Grain boundary character distributions in nanocrystalline metals produced by different processing routes

TL;DR

This study compares grain boundary character distributions in nanocrystalline Ni alloys produced by different methods, revealing significant variations that impact material properties like corrosion resistance.

Contribution

It provides the first detailed comparison of grain boundary character distributions across multiple processing routes in nanocrystalline metals.

Findings

Deposited Ni alloys have similar grain boundary distributions with high {\

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Abstract

Nanocrystalline materials are defined by their fine grain size, but details of the grain boundary character distribution should also be important. Grain boundary character distributions are reported for ball milled, sputter deposited, and electrodeposited Ni and Ni-based alloys, all with average grain sizes of ~20 nm, to study the influence of processing route. The two deposited materials had nearly identical grain boundary character distributions, both marked by a {\Sigma}3 length percentage of 23-25%. In contrast, the ball milled material had only 3% {\Sigma}3-type grain boundaries and a large fraction of low angle boundaries (16%), with the remainder being predominantly random high angle (73%). These grain boundary character measurements are connected to the physical events that control their respective processing routes. Consequences for material properties are also discussed with a focus on nanocrystalline corrosion. As a whole, the results presented here show that grain boundary character distribution, which has often been overlooked in nanocrystalline metals, can vary significantly and influence material properties in profound ways.