Observation of S = 1/2 quasi-one-dimensional magnetic and magneto-dielectric behavior in a cubic SrCuTe2O6

TL;DR

This study reveals that SrCuTe2O6 exhibits quasi-one-dimensional magnetic behavior with magneto-dielectric effects, despite structural similarities to a three-dimensional frustrated magnet, highlighting the dominance of third nearest neighbor couplings.

Contribution

It demonstrates that SrCuTe2O6, structurally similar to PbCuTe2O6, shows quasi-one-dimensional magnetic properties driven by third nearest neighbor interactions, with observable magneto-dielectric effects.

Findings

Broad susceptibility maximum at 32 K

Magnetic ordering at 5.5 K and 4.5 K

Magneto-dielectric anomalies at ordering temperatures

Abstract

We investigate magnetic, thermal, and dielectric properties of SrCuTe2O6, which is isostructural to PbCuTe2O6, a recently found, Cu-based 3D frustrated magnet with a corner sharing triangular spin network having dominant first and second nearest neighbor (nn) couplings [B. Koteswararao, et al. Phys. Rev. B 90, 035141 (2014)]. Although SrCuTe2O6 has a structurally similar spin network, but the magnetic data exhibit the characteristic features of a typical quasi -one-dimensional magnet, which mainly resulted from the magnetically dominant third nn coupling, uniform chains. The magnetic properties of this system are studied via magnetization (M), heat capacity (Cp), dielectric constant, measurements along with ab-initio band structure calculations. Magnetic susceptibility chi(T) data show a broad maximum at 32 K and the system orders at low temperatures TN1=5.5 K and TN2=4.5 K, respectively. The analysis of chi(T) data gives an intra-chain coupling, J3/kB, to be about - 42 K with non-negligible frustrated inter-chain couplings (J1/kB and J2/kB). The hopping parameters obtained from LDA band structure calculations also suggest the presence of coupled uniform chains. The observation of simultaneous anomalies in dielectric constant at TN1 and TN2 suggests the presence of magneto-dielectric effect in SrCuTe2O6. A magnetic phase diagram is also built based on M, C p, and dielectric constant results.