Stanene: Atomically Thick Free-standing Layer of 2D Hexagonal Tin

TL;DR

This paper reports the synthesis and optical characterization of atomically thin stanene, a 2D tin layer with promising topological insulator properties due to its strong spin-orbit coupling, supported by first-principles calculations.

Contribution

It introduces the synthesis of free-standing few-layer stanene and combines experimental optical analysis with theoretical calculations to explore its properties.

Findings

Successfully synthesized mono to few-layer stanene

Optical properties characterized by UV-Vis, Raman, and photoluminescence

First-principles calculations support experimental observations

Abstract

Two dimensional (2D) layered materials have recently gained renewed interest due to their exotic electronic properties along with high specific surface area. The prospects of exploiting these properties in sensing, catalysis, energy storage, protective coatings and electrochromism have witnessed a paradigm shift towards the exploration of these sophisticated 2D materials. The exemplary performance of graphene (1) which is among the first of these elemental 2D materials have initiated a runaway effect in the pursuit of studying alternative 2D materials. Even though graphene has tunable exotic electronic properties (2), the spin-orbit (SO) coupling is weak (3) limiting its applications as spin filters, topological insulators etc. Topological insulators by their very nature force the electrons to travel on the surface at very high speeds thereby finding useful applications in electronic and photonic devices. Exploration of group IV elements using first principles calculations have revealed that the SO coupling increases as the atomic weight of the basis atoms in the honeycomb lattice (4). Tin is one of the heaviest elements in this series having strong spin-orbit coupling making it a promising applicant for room temperature topological insulator. Thus there is an urgent need to discover novel 2D materials in the post graphene age to overcome its deficiencies. We have synthesized and investigated the optical transitions in 2D material referred to as few-layer stanene (FLS). These are analogous to few-layer graphene and can be visualized by replacing carbon atoms by tin on a graphene lattice. We have been able to synthesize from mono to few atomic layers of free standing stanene and characterize them optically using UV-Vis absorption, Raman and photoluminescence spectroscopy. First principles calculations have been performed to interpret experimental results.